(4-Fluorophenyl)(2-hydroxy-5-methylphenyl)methanone
نویسندگان
چکیده
In the title compound, C14H11FO2, the dihedral angles beteen the central C3O ketone residue and the fluoro- and hy-droxy-substituted benzene rings are 50.44 (9) and 12.63 (10)°, respectively. The planes of the benzene rings subtend a dihedral angle of 58.88 (9)° and an intra-molecular O-H⋯O hydrogen bond closes an S(6) ring. No directional inter-actions beyond van der Waals packing contacts were identified in the crystal structure.
منابع مشابه
(4-Fluorophenyl)(4-hydroxy-3-methylphenyl)methanone
In the title compound, C14H11FO2, the two benzene rings are not coplanar, with a dihedral angle of 57.45 (12)° between their planes. In the crystal, mol-ecules are linked by an O-H⋯O hydrogen bond, forming a 21 helical chain along the b axis.
متن کامل(2-Hydroxy-7-methoxynaphthalen-1-yl)(4-methylphenyl)methanone
In the title compound, C(19)H(16)O(3), an intra-molecular O-H⋯O=C hydrogen bond is formed between the hy-droxy and carbonyl groups on the naphthalene ring system, resulting in an S(6) ring. The angles between the C=O bond vector and the least-squares planes of the naphthalene ring system and the benzene ring are 27.63 (6) and 47.99 (7)°, respectively. The dihedral angle between the latter plane...
متن کامل(4-Hydroxy-3-methylphenyl)(phenyl)methanone
In the title compound, C14H12O2, the benzene rings make a dihedral angle of 58.84 (12)°. In the crystal, mol-ecules are linked into chains along the b-axis direction by O-H⋯O hydrogen bonds. These chains are further linked by C-H⋯O hydrogen bonds, forming layers parallel to the bc plane.
متن کامل(5-Bromo-2-methylphenyl)(4-ethoxyphenyl)methanone
In the title compound, C(16)H(15)BrO(2), the dihedral angle between the benzene rings is 68.5 (2)°. In the crystal structure, mol-ecules are linked by weak C-H⋯O hydrogen bonds into chains parallel to the b axis.
متن کاملN-[Bis(4-fluorophenyl)methylene]aniline
The title compound, C(19)H(13)F(2)N, was synthesized by an addition reaction of bis-(4-fluoro-phen-yl)methanone with aniline. The dihedral angles formed by the fluoro-benzene rings with the aniline ring are 81.04 (5) and 64.15 (5)°. In the crystal packing, inter-molecular C-H⋯F hydrogen bonds link mol-ecules into zigzag chains parallel to the c axis.
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عنوان ژورنال:
دوره 70 شماره
صفحات -
تاریخ انتشار 2014